1,2-Bis(N′-benzoylthioureido)-4-chlorobenzene

1-(3-Bromopropoxy)-4-chlorobenzene

In the mol-ecule of the title compound, C(8)H(8)BrClO, the Cl atom lies slightly out of the aromatic ring plane [displacement = 0.072 (3) Å]. In the crystal structure, a π-π contact between the phenyl rings [centroid-centroid distance = 3.699 (3) Å] may stabilize the structure. There also exists a C-H⋯π contact between the methyl-ene group and the chloro-phenyl ring.

The Solvation and Dissociation of 4‐Benzylaniline Hydrochloride in Chlorobenzene

A reaction scheme is proposed to account for the liberation of 4-benzylaniline from 4-benzylaniline hydrochloride, using chlorobenzene as a solvent at a temperature of 373 K. Two operational regimes are explored: “closed” reaction conditions correspond to the retention of evolved hydrogen chloride gas within the reaction medium, whereas an “open” system permits gaseous hydrogen chloride to be r...

Topical immunotherapy with dinitro-chlorobenzene: safety concerns.

Cover vol. 12, no.4, August 2015-

Atomic-scale surface demixing in a eutectic liquid BiSn alloy.

Resonant x-ray reflectivity of the surface of the liquid phase of the Bi(43)Sn(57) eutectic alloy reveals atomic-scale demixing extending over three near-surface atomic layers. Because of the absence of an underlying atomic lattice which typically defines adsorption in crystalline alloys, studies of adsorption in liquid alloys provide unique insight on interatomic interactions at the surface. T...